Metal-H systems : basic knowledge

This page gathers some important and inevitable
Reviews, Chapters, Books, Lessons, ... about Metal-H systems.

Why such an on-line library ? It's as simple as that : we here want to make available something we would have loved to find when we did start in the MH field.
We hope that with them in hands, you have a minimum fertile ground for future good and relevant contributions :)
But, as said in our recent MH-2024 Poster (see block 5), we need your help to complete and improve this page !

The long term goal of this page is to propose a useful library (clear and well organized) where general materials will be available, as well as materials on specific given subjects. Here, the objective is to centralize the information to limit any waste of time for the beginner.
Besides, we'd love to make available here the materials that was given during Summer Schools in previous M-H-Conference-series. We work on it.
Apart that, a natural and logical evolution of this page will likely be participative : strength is found through unity --> the more we are, the better it is --> with the aim to producing a substantial, relevant, reliable and well organized content.
This page is under construction ...
We just need time to insert, introduce and sort all the Books, Chapters, Reviews, etc ... we already have. And ... there are a lot ! A lot !
What you see below is just a very beginning : it's the minimum of the minimum of the minimum of the minimum of ... . In brief : the minimum.

Table of Content

To find a given item :
just use CTRL + F on your keyboard


1) General Material
 1.a) Old general books : < 1970      
   D.P. Smith (1948)
   K.M. Mackay (1966)
   Müller / Blackledge / Libowitz (1968)
 1.b) The Bible # 1 : "Hydrogen in Metals" three-volume set (1978/1978/1997)
 1.c) The Bible # 2 : "Fukai's book" (1993/2005)
 1.d) The Bible # 3 : R. Griessen's Lecture notes  
 1.e) Other important books and large reviews
   1.e.1) Hydrogen in intermetallic compounds I (1988) Schlapbach editor
   1.e.2) Hydrogen in intermetallic compounds II (1992) Schlapbach editor
   1.e.3) Metal Hydrides (1981) Bambakidis editor
   1.e.4) Electronic structure and properties of Hydrogen in Metals (1983) Jena and Satterthwhaite editors
   1.e.5) The physical and metallurgical aspects of Hydrogen in Metals (1994) by Oriani
   1.e.6) Progress in Hydrogen Treatment of Materials (2001) Goltsov editor
   1.e.7) Hydrogen in Metals : microstructural aspects (2006) by Pundt and Kirchheim
   1.e.8) Hydrogen in metals (Chap. 25) : in Physical Metallurgy, 5th Edition (2014) by Pundt and Kirchheim
   1.e.9) Hydrogen storage materials : the characterization of their storage properties (2011) by Broom
   1.e.10) Hydrogen interactions with defects in materials (2024) by Pundt and Wagner
   1.e.11) Hydrogen Metal Systems I (1996) and II (2000) by F.A. Lewis and A. Aladjem editors
  
2) Phase diagrams (handbooks)
 2.a) Phase Diagrams : Binary Alloys (including M-H systems)
   2.a.1) Hansen 1958 / Elliott 1965 / Shunk 1969
   2.a.2) Massalski 1986 / Massalski 1990
   2.a.3) ASM Metal Handbook : volume 3 : Alloy phase diagrams (1992/2016)
   2.a.4) Landolt Börnstein : Phase equilibria, crystallographic and thermodynamic data of binary alloys (1991-2016)
   2.a.5) Phase diagrams of Binary Hydrogen alloys (2000) by F.D. Manchester
   2.a.6) Desk Handbook phase diagrams for binary alloys (2000/2010)
 2.b) Phase diagrams : Ternary alloys (including M-H systems)
   2.b.1) Landolt Börnstein : Ternary alloy systems - Phase diagrams, Crystallographic and thermodynamic data (2004-2010)
 2.c) Phase diagrams : elements and alloys under HIGH PRESSURES (including M-H systems)
   2.c.1) Elements : D.A. Young (1975 and its extension/update 1991)
   2.c.2) Elements : E. Yu Tonkov and E.G. Ponyatovsky (1979 and its extension/update 2005)
   2.c.3) Alloys and compounds : E. Yu Tonkov (a six-volume series 1992-2007 + a stand-alone volume 1998)

3) Crystallographic data (handbooks)
 3.a) Pearson I (1958)
 3.b) Pearson II (1967)
 3.c) Pearson III (ASM 1st Edition) (1985)
 3.d) Pearson IV (ASM 2nd Edition) (1991)
 3.e) Pearson V (ASM Desk Edition) (1997)

...

15) Special collection
 15.a) Videos of brittle metals pulverized by the first H absorption
   15.a.1) Video of ZrMn1.5 decrepitation
   15.a.2) Video of LaNi5 decrepitation
   15.a.3) a recent (2024) review about degradation mechanisms observed in interstitial metal hydrides for H storage
 15.b) History of International Symposiums on Metal-Hydrogen systems
 15.c) History of GRC / GRS Conferences
N.B. : all papers / chapters / books mentioned in this page can be downloaded via LibGen or Sci Hub
(except : those directly downloadable thanks to the blue/black boxes, or a few exceptions).
Via Sci-Hub : just enter the DOI number, bingo !
Via Libgen : just enter the keys words, bingo !

1) General Material

 
 

1.a) Old general books : < 1970

Photo by N.A.

Hydrogen in Metals
D.P. Smith
1948
367 pages

How to download it :
- go to the "LibGen" website,
- and enter "hydrogen in metals smith",
- bingo !
The version available in the LibGen website was scanned by The i2-HMR.
N.B. : at the time of the scan, this book was not available from Publishers (and is maybe still not), explaining why we shared it in LibGen. We're sorry for the low quality of the scan.


Hydrogen compounds of the metallic elements


K.M. Mackay
1966
186 pages

How to download it :
- go to the "LibGen" website,
- and enter "hydrogen compounds of the metallic elements",
- bingo !
The version available in the LibGen website was scanned by The i2-HMR.
N.B. : at the time of the scan, this book was not available from Publishers (and is maybe still not), explaining why we shared it in LibGen. We're sorry for the low quality of the scan.

Photo by N.A.

Metal Hydrides
W.M. Müller
J.P. Blackledge
G.G. Libowitz
1968
795 pages

How to find this book :
DOI : 10.1016/C2013-0-12462-2

If it doesn't work with Sci-Hub, use LibGen :
- go to the "LibGen" website,
- and enter "metal hydrides",
- bingo !

1.b) The Bible # 1 : "Hydrogen in Metals" three-volume set

Hydrogen in Metals I :
basic properties

Editors : G. Alefeld and J. Völkl
1978
431 pages

How to find this book :
DOI : 10.1007/3-540-08705-2


Hydrogen in Metals II :
application-oriented properties

Editors : G. Alefeld and J. Völkl
1978
404 pages

How to find this book :
DOI : 10.1007/3-540-08883-0

Hydrogen in Metals III :
properties and applications

Editor : H. Wipf
1997
359 pages

How to find this book :

1.c) The Bible # 2 : "Fukai's Book"

The Metal-Hydrogen system :
basic bulk properties

Y. Fukai
2005 (2nd edition)
506 pages

How to find this book :
DOI : 10.1007/3-540-28883-X


The previous edition (1993) can be found here.


1.d) The Bible # 3 : R. Griessen's Lecture notes


Prof. Dr. Ronald Griessen
Faculty of Sciences
VU University
The Netherlands

Lecture notes can be found HERE, in R. Griessen's University WEBSITE.
It is also possible to download these lecture notes via an all-in-one PDF by clicking on the picture below.


1.e) Other important books and large reviews

 

1.e.1) Hydrogen in intermetallic compounds I (1988) Schlapbach editor

Part I : 
electronic, thermodynamic and crystallographic properties, preparation

Edited by L. Schlapbach.
Year : 1988.
Pages : 350.
How to find this book :
DOI : 10.1007/3-540-18333-7


1.e.2) Hydrogen in intermetallic compounds II (1992) Schlapbach editor

Part II :
surface and dynamics properties, applications

Edited by L. Schlapbach.
Year : 1992.
Pages : 328.
How to find this book :
DOI : 10.1007/3-540-54668-5


1.e.3) Metal Hydrides (1981) Bambakidis editor

Metal Hydrides

Edited by B. Bambakidis.
Year : 1981.
Pages : 385.
How to find this book :
DOI : 10.1007/978-1-4757-5814-6


1.e.4) Electronic structure and properties of Hydrogen in Metals (1983) Jena and Satterthwhaite editors

Electronic structure and properties of Hydrogen in Metals

Edited by P. Jena and C.B. Satterthwaite.
Year : 1983.
Pages : 698.
How to find this book :
DOI : 10.1007/978-1-4684-7630-9


1.e.5) The physical and metallurgical aspects of Hydrogen in Metals (1994) by Oriani

The physical and metallurgical aspects of Hydrogen in Metals

By R.A. Oriani.
Reference : Transactions of Fusion Technology, Vol. 26, issue 4T (1994) 235-266.

How to find this review ?
There are 2 ways.
(i) The first way is to download it directly thanks to the box below, since the publisher does not make it available in its website (at least on Nov. 25th 2020) ; this paper has no DOI number. You can check whether the situation has changed directly in the publisher's website : here. This version is the ORIGINAL one, kindly supplied by Prof. Dieter H. Britz in 2014 to Nicolas Armanet (thanks a lot !).

(ii) The other way is to download it via the LENR-CANR.org website HERE. This version is not the original one, but is much more enjoyable to read (and with better resolution photos).



1.e.6) Progress in Hydrogen Treatment of Materials (2001) Goltsov editor

Progress in Hydrogen Treatment of Materials

Edited by V.A. Goltsov.
Year : 2001.
Pages : 545.

How to download it :
- go to the "LibGen" website,
- and enter "progress in hydrogen treatment",
- bingo !


1.e.7) Hydrogen in Metals : microstructural aspects (2006) by Pundt and Kirchheim

Hydrogen in Metals : microstructural aspects

By A. Pundt and R. Kirchheim.
Reference : Annu. Rev. Matter Res., 36 (2006) 555-608.

How to find this review :
DOI : 10.1146/annurev.matsci.36.090804.094451

Note that prior to this 2006 review,  Pundt and Kirchheim also wrote two important reviews : 

(i) Hydrogen in nano-sized metals, A. Pundt, 2004, 11 pages,

(ii) Solid solutions of hydrogen in complex materials, R. Kirchheim, 2004, 88 pages.


1.e.8) Hydrogen in metals (Chap. 25) : in Physical Metallurgy, 5th Edition (2014) by Pundt and Kirchheim

Chapter 25 : Hydrogen in Metals

in : Physical Metallurgy (5th Edition).
By : A. Pundt and R. Kirchheim.
Year : 2014.
How to find this review :

This chapter is an extended and updated version of their previous (2006) review paper (see 1.e.7).




1.e.9) Hydrogen storage materials : the characterization of their storage properties (2011) by Broom

Hydrogen storage materials :
the characterization of their storage properties

By : D.P. Broom.
Year : 2011.

How to find this book :

Download the Table of Content


1.e.10 Hydrogen interactions with defects in materials (2024) by Pundt and Wagner

Hydrogen interactions with defects in materials
by A. Pundt and S. Wagner.
Reference : Chem. Ing. Tech., 96 (2024) 1-11 (page numbers not final).

How to find this review :

This relatively short review paper is built on the basis of their previous bigger review articles (see 1.e.7 and 1.e.8), including recent developments.

 

1.e.11) Hydrogen Metal Systems I (1996) and II (2000) by F.A. Lewis and A. Aladjem editors

 
This 2-volume set "Hydrogen Metal Systems I & II" presents comprehensive information and critical data concerning ionic and metallic hydrides ; all conveniently based upon a periodic-table layout.
 
from the publisher
Hydrogen Metal Systems I (1996)
 

Hydrides covered in this book

  • Lithium-Hydrogen
  • Sodium, Potassium, Cesium and Rubidium Hydrides
  • Magnesium (Beryllium) and Alkaline Earth (Calcium, Strontium and Barium) Hydrides
  • Rare Earths-Hydrogen
  • Actinides-Hydrogen
  • Titanium-Hydrogen
  • Zirconium-Hydrogen
  • Hafnium-Hydrogen
  • Vanadium-, Niobium- and Tantalum-Hydrogen
  • Tritium in Metals

Editors : F.A. Lewis and A. Aladjem.

Year : 1996.

Published in : "Solid State Phenomena" as Volumes 49-50, by "Trans Tech Publications", Switzerland.

Pages : 474.

Table of Content : https://www.scientific.net/book/hydrogen-metal-systems-i/978-3-0357-0662-8_toc.pdf.

Preface : https://www.scientific.net/SSP.49-50.-1.pdf.

 
from the publisher
 
Hydrogen Metal Systems II (2000)
 
Hydrides covered in this book :
  • Chromium-, Molybdenum- and Tungsten-Hydrogen
  • Manganese-, Technetium- and Rhenium-Hydrogen
  • Iron (Ruthenium and Osmium)-Hydrogen
  • Cobalt-, Rhodium- and Iridium-Hydrogen
  • Nickel-Hydrogen
  • Platinum-Hydrogen
  • Palladium-Platinum alloy-Hydrogen
  • Palladium-Hydrogen
  • Copper- Silver- and Gold-Hydrogen

Editors : F.A. Lewis and A. Aladjem.

Year : 2000.

Published in : "Solid State Phenomena" as Volumes 73-75, by "Trans Tech Publications", Switzerland.

Pages : 526.

Table of Content : https://www.scientific.net/book/hydrogen-in-metal-systems-ii/978-3-0357-0698-7_toc.pdf.

Preface : https://www.scientific.net/SSP.73-75.-1.pdf.

How to find these books :
Apparently, each book can't be downloaded as a whole ; instead, it is possible to download each Chapter independently using its DOI number :
- as for "Hydrogen Metal Systems I", go to https://www.scientific.net/SSP.49-50, then select the wanted Chapter, and then use its DOI number (via Sci-Hub if you don't have access with your Institution),
- as for "Hydrogen Metal Systems II", go to https://www.scientific.net/SSP.73-75, then select the wanted Chapter, and then use its DOI number (via Sci-Hub if you don't have access with your Institution).

2) Phase Diagrams (handbooks)

IMPORTANT NOTE * : 

phase diagrams in 2.a and 2.b do overwhelmingly concern phase transformations occurring at normal pressure - although these Handbooks (detailed in 2.a and 2.b) do still contain some data on phase transformations under high pressure, but they are scattered and unsystematized. The section 2.c gathers Handbooks which are focused on phase transformations under high pressures.

* as justly evoked by E. Yu. Tonkov in the Preface of his Vol. 7 (1998) described in section 2.c.3.


2.a) Phase Diagrams : Binary Alloys (including M-H systems)

2.a.1) Hansen 1958 / Elliott 1965 / Shunk 1969

a photo of our own version

Hansen (1958) = vol. 1

Title : Constitution of binary alloys.
Authors : M. Hansen and K. Anderko.
Year : 1958 (2nd edition).
Pages : 1305.

How to download it :
- go to the "LibGen" website,
- and enter "constitution of binary alloys hansen",
- bingo !
The version available in the LibGen website was scanned by The i2-HMR.
N.B. : at the time of the scan, this book was not available from Publishers (and is maybe still not), explaining why we shared it in LibGen. We're sorry for the low quality of the scan.

a photo of our own version

Elliott (1965) = vol. 2

Title : Constitution of binary alloys, first supplement.
Author : R.P. Elliott.
Year : 1965.
Pages : 877.

How to download it :
- go to the "LibGen" website,
- and enter "constitution of binary alloys elliott",
- bingo !
The version available in the LibGen website was scanned by The i2-HMR.
N.B. : at the time of the scan, this book was not available from Publishers (and is maybe still not), explaining why we shared it in LibGen. We're sorry for the low quality of the scan.

a photo of our own version

Shunk (1969) = vol. 3

Title : Constitution of binary alloys, second supplement.
Author : F.A. Shunk.
Year : 1969.
Pages : 720.

How to download it :
- go to the "LibGen" website,
- and enter "constitution of binary alloys shunk",
- bingo !
The version available in the LibGen website was scanned by The i2-HMR.
N.B. : at the time of the scan, this book was not available from Publishers (and is maybe still not), explaining why we shared it in LibGen. We're sorry for the low quality of the scan.


2.a.2) Massalski 1986 / Massalski 1990

photo from abebooks.com

Massalski,
1st edition, 1986, ASM

Title : Binary alloy phase diagrams.
Editors : T.B. Massalski and J.L. Murray, L.H. Bennett, H. Baker.
Year : 1986.
Vol 1 : Ac-Au to Fe-Rh.
Vol 2 : Fe-Ru to Zn-Zr.
Pages (total) : 2224.

How to download it :
- go to the "LibGen" website,
- and enter "binary alloy phase diagrams",
- bingo !

photo from the ASM website

Massalski,
2nd edition, 1990, ASM

Title : Binary alloy phase diagrams.
Editors : T.B. Massalski, H. Okamoto, P.R. Subramanian, L. Kacprzak.
Year : 1990.
Vol 1 : Ac-Ag to Ca-Zn (970 pages).
Vol 2 : Cd-Ce to Hf-Rb (2104 - 971 pages = 1133 pages).
Vol 3 : Hf-Re to Zn-Zr

How to find it :
ASM : see this link.
LibGen : not present yet.

important note :

a desk edition of this 1990 three-volume set is now available (with updates made in 2000 and in 2010) : see section 2.a.6.


2.a.3) ASM Metal Handbook : volume 3 : Alloy phase diagrams (1992/2016)

photo from abebooks.com

1992 edition

How to download it :
- go to the "LibGen" website,
- and enter "alloy phase diagrams",
- bingo !

photo from the ASM website

2016 edition

Editors : H. Okamoto, M.E. Schlesinger, E.M. Mueller.

Can be found via the ASM website here :
- either this link,
- or this link,
- or this link.
LibGen : not present yet.


2.a.4) Landolt Börnstein : Phase equilibria, crystallographic and thermodynamic data of binary alloys (1991-2016)

Group IV, Physical Chemistry

(i) Volume 5A, 1991 : Ac-Au -- Au-Zr.
Editor : O. Madelung.
(ii) Supplement to 5A = Volume 12A, 2006 : Ac-Ag -- Au-Zr.
Editor : B. Predel.
(iii) Volume 5B, 1992 : B-Ba -- C-Zr.
Editor : O. Madelung.
(iv) Volume 5C, 1993 : Ca-Cd -- Co-Zr.
Editor : O. Madelung.
(v) Volume 5D, 1994 : Cr-Cs -- Cu-Zr.
Editor : O. Madelung.
(vi) Supplement to 5B, 5C, 5D = Volume 12B, 2012 : B-Ba -- Cu-Zr.
Editor : B. Predel.
(vii) Supplement to 5B, 5C, 5D = Volume 12C, 2013 : Dy-Er -- Ir-Y.
Editor : B. Predel.
(viii) Supplement to 5B, 5C, 5D = Volume 12D, 2016 : K-O -- Y-Zr.
Editor : F. Predel.
(ix) Volume 5E, 1995 : Dy-Er -- Fr-Mo.
Editor : O. Madelung.
(x) Volume 5F, 1996 : Ga-Gd -- Hf-Zr.
Editor : O. Madelung.
(xi) Volume 5G, 1997 : Hg-Ho -- La-Zr.
Editor : O. Madelung.
(xii) Volume 5H, 1997 : Li-Mg -- Nd-Zr.
Editor : O. Madelung.
(xiii) Volume 5I, 1998 : Ni-Np -- Pt-Zr.
Editor : O. Madelung.
(xiv) Volume 5J, 1998 : Pu-Re -- Zn-Zr.
Editor : O. Madelung.

All these volumes can be found via LibGen (except : (i) and (viii)) :
 - go to the "LibGen" website,
- and enter for instance "Ac-Ag -- Au-Zr",
- bingo !

--> (i) and (viii) are not yet on LibGen, regretfully.
Photo from Amazon

 

2.a.5) Phase diagrams of Binary Hydrogen alloys (2000) by F.D. Manchester

Important note : 
although the above 2.a.1 - 2.a.4 Binary alloys HandBooks do include many M-H systems, the present HandBook is solely dedicated to M-H systems. 
Note nevertheless that this MonoGraph was published in 2000 and therefore some more recent informations might be available in 2.a.3 and 2.a.4 since they have been updated in 2016 (for the former) and in 2006-2016 (for the last).

Title : Phase diagrams of Binary Hydrogen alloys,
In the series : Monograph series on alloy phase diagrams, Vol. 13,
Publisher : ASM International,
Editor : F.D. Manchester,
Year : 2000,
Pages : 322.

How to download it (regretfully there's no solution for the moment) :
ASM website : not present.
LibGen : not present yet.

Special thanks to Dr. Jean-Marc Joubert (ICMPE/CNRS-UPEC, France) for this suggestion (of Handbook to be added in our on-line Library) -- suggestion made in the framework of our recent MH-2024 Poster calling for help from long-experienced Hydriders :).

Personal note : see emails 4a-4c in the MH-2024 folder --> Abstracts --> Le notre --> emails avec Joubert.
from Amazon

2.a.6) Desk Handbook phase diagrams for binary alloys (2000/2010)

Important note :

this stand-alone handbook (with a 1st edition in 2000 and a 2nd edition in 2010) is built up on the three-volume set Massalski 1990 (described in section 2.a.2). New and/or updated phase diagrams collected in the period 1990 - 2000 (for the 1st edition) and in the period 2000 - 2010 (for the 2nd edition) are included. To fit into a single volume (i.e. into a desk edition) the size of the phase diagrams has been reduced (in regards to those presented in Massalski 1990's three-volume set) and only the "best" diagram is selected per system. Also, the number of data sources is reduced.

Desk Handbook
1st ed., 2000, ASM

Title : Desk handbook phase diagrams for binary alloys, first edition.
Editor : Hiroaki Okamoto.
Year : 2000.
Pages : 828.

How to download this handbook :
- from the ASM's website : not available (checked on Sept. 02nd 2024).
- from LibGen : unfortunately, not available neither  (checked on Sept. 02nd 2024).

from Abebooks
from Amazon

Desk Handbook
2nd ed., 2010, ASM

Title : Desk handbook phase diagrams for binary alloys, second edition.
Editor : Hiroaki Okamoto.
Year : 2010.
Pages : 900.

How to download this handbook :
- from the ASM's website : https://www.asminternational.org/home/-/journal_content/56/10192/57751G/PUBLICATION.
- from LibGen : unfortunately, not available yet (checked on Sept. 02nd 2024).

Table of Content (TOC) : is available from the publisher at this address.


2.b) Phase Diagrams : Ternary Alloys (including M-H systems)

 

2.b.1) Landolt Börnstein : Ternary alloy systems - Phase diagrams, Crystallographic and thermodynamic data (2004-2010)

Group IV, Physical chemistry
Volume 11

Subvolume A : Light metal systems
(i) Part 1, Selected systems, 2004 : Ag-Al-Cu -- Al-Cu-Er
Editors : G. Effenberg and S. Ilyenko.
(ii) Part 2, Selected systems, 2005 : Al-Cu-Fe -- Al-Fe-Ti
Editors : G. Effenberg and S. Ilyenko.
(iii) Part 3, Selected systems, 2005 : Al-Fe-V -- Al-Ni-Zr
Editors : G. Effenberg and S. Ilyenko.
(iv) Part 4, Selected systems, 2006 : Al-Si-Ti -- Ni-Si-Ti
Editors : G. Effenberg and S. Ilyenko.

Subvolume B : Noble metal systems
(v) Selected systems, 2006 : Ag-Al-Zn -- Rh-Ru-Sc
Editors : G. Effenberg and S. Ilyenko.

Subvolume C : Non-ferrous metal systems
(vi) Part 1, Selected semiconductor systems, 2006 : Ag-As-S -- In-Sb-Se
Editors : G. Effenberg and S. Ilyenko.
(vii) Part 2, Selected Copper systems, 2007 : Al-Cu-Li -- Cu-Ti-Zn
Editors : G. Effenberg and S. Ilyenko.
(viii) Part 3, Selected soldering and brazing systems, 2007 : Ag-Bi-Cu -- Ni-Pd-Si
Editors : G. Effenberg and S. Ilyenko.
(ix) Part 4, Selected nuclear materials and engineering systems, 2007 : Al-Fe-U -- Th-U-Zr
Editors : G. Effenberg and S. Ilyenko.

Subvolume D : Iron systems
(x) Part 1, Selected systems, 2008 : Al-B-Fe -- C-Co-Fe
Editors : G. Effenberg and S. Ilyenko.
(xi) Part 2, Selected systems, 2008 : C-Cr-Fe -- Co-Fe-S
Editors : G. Effenberg and S. Ilyenko.
(xii) Part 3, Selected systems, 2008 : Co-Fe-Si -- Cu-Fe-Pt
Editors : G. Effenberg and S. Ilyenko.
(xiii) Part 4, Selected systems, 2008 : Cu-Fe-Si -- Fe-N-U
Editors : G. Effenberg and S. Ilyenko.
(xiv) Part 5, Selected systems, 2009 : Fe-N-V -- Fe-Ti-Zr
Editors : G. Effenberg and S. Ilyenko.

Subvolume E : Refractory systems
(xv) Part 1, Selected systems, 2009 : Al-B-C -- B-Hf-W
Editors : G. Effenberg and S. Ilyenko.
(xvi) Part 2, Selected systems, 2010 : B-Mo-Ni -- C-Ta-Ti
Editors : G. Effenberg and S. Ilyenko.
(xvii) Part 3, Selected systems, 2010 : C-Ta-W -- Ti-V-W
Editors : G. Effenberg and S. Ilyenko.

ALL the above volumes can be found via LibGen, although there's a trick for each :
======================================
The following volumes can be found via LibGen :
(i)-(v) + (x)-(xiii) + (xv)-(xvii)
this way :
 - go to the "LibGen" website,
- and enter the three first elements, e.g. "C-Ta-W",
- bingo !
=======================================
The following volumes can be found via LibGen :
(vi)-(ix)
this way :
 - go to the "LibGen" website,
- and enter e.g. "selected semiconductor systems",
- bingo !
======================================
The following volume can be found via LibGen :
(xiv)
this way :
 - go to the "LibGen" website,
- and enter "11D5",
- bingo !
======================================

Hydrides covered in these volumes :

(iii) 11A3 :
Al-H-Li
Al-H-Mg
Al-H-Ti

(iv) 11A4 :
H-Mg-Ni

(v) 11B :
Ag-H-Pd
Au-H-Pd
Cu-H-Pd
H-Ni-Pd
H-Pd-Pt
H-Pd-Rh

(vii) 11C2 :
Cu-H-Ni

(x) 11D1 :
Al-Fe-H

(xi) 11D2 :
C-Fe-H

(xii) 11D3 :
Cr-Fe-H

(xiii) 11D4 :
Fe-H-Mn
Fe-H-Mo
Fe-H-Ni
Fe-H-O
Fe-H-P
Fe-H-Si
Fe-H-V

????!!!! In case of :
other hydrides are addressed in these volumes BUT we missed them : please don't hesitate to tell us so ! Thanks ;)

2.c) Phase diagrams : elements and alloys under HIGH PRESSURES (including M-H systems)

IMPORTANT NOTES :


(i) Normal pressure (phase diagrams) vs High pressure (phase diagrams)*

Phase diagrams in 2.a and 2.b do overwhelmingly concern phase transformations occurring at normal pressure - although these Handbooks (detailed in 2.a and 2.b) do still contain some data on phase transformations under high pressure, but they are scattered and unsystematized. The present section 2.c gathers Handbooks which are focused on phase transformations under high pressures.

* as justly evoked by E. Yu. Tonkov in the Preface of his Vol. 7 (1998) described in section 2.c.3.


(ii) In this section 2.c two kind of compilations are presented, both regarding phase transformations under high pressures :
- the first sub-sections (2.c.1 and 2.c.2) deals with the elements (i.e. as single components),
- the second sub-section (2.c.3) deals with compounds and alloys (binary, ternary, ...), which include M-H systems.

(iii) It might seem bizarre to addressing phase diagrams of the elements in such website (which deals with M-H systems) but there's a good reason behind : for those interested by high-pressure properties of a given M-H system, it is of great significance to already have in hands the high-pressure behaviour of the parent metal itself (i.e. of the metal itself before it absorbs Hydrogen).

(iv) The urgent need to update these high-pressure handbooks
All the handbooks presented in this section 2.c cover literature up to 1991 - 2007. Despite the fact that such handbooks on phase transformations (phase diagrams) under high pressure constitute a UNIQUE compilation, one has to stress that given the CONSIDERABLE progress* made during these last 20 years (say, from 2007 to now 2024) it is very urgent to find a way to update these handbooks. This is somehow a call to both the High-Pressure and the M-H fields ;) .
* thanks to : an even more extended maximal attainable pressure (in high pressure cells) + a massive use of high pressure cells (like DAC) in synchrotrons worldwide + the enthusiasm for room temperature superconductivity. Such a situation has produced an explosion of new experimental and theoretical results.

2.c.1) Elements : D.A. Young (1975 and its extension/update 1991)

from the document itself

Phase diagrams of the elements, 1975

Title : Phase diagrams of the elements.
Author : David A. Young.
"Publisher" : Lawrence Livermore Laboratory Report (UCRL-51902).
Year : September 1975.
Pages (total) : 70.

How to download it :
- go to this https://www.osti.gov/servlets/purl/4010212,
- bingo !

from Amazon

Phase diagrams of the elements, 1991
(= update and extension of the 1975 report)

Title : Phase diagrams of the elements.
Author : David A. Young.
Publisher : University of California Press.
Year : 1991.
Pages : 291.

How to download it :
(i) either via the official link, using this DOI number : https://doi.org/10.1525/9780520911482,
(ii) or via LibGen :
- enter "phase diagrams of the elements",
- choose the "Reprint 2020 ed.",
- bingo !


2.c.2) Elements : E. Yu Tonkov and E.G. Ponyatovsky (1979 and its extension/update 2005)

from the document itself

Phase diagrams of the elements at high pressure, 1979

Original title (in Cyrillic alphabet) : Фазовые диаграммы элементов при высоком давлении. As far as we know, this book has been published in Russian, and not in English.
Title in Latin Alphabet : Fazoviye Diagrammy Elementov pri Vysokom Davleniya.
Title in English : Phase diagrams of the elements at high pressure.
Author : E. Yu Tonkov.
Publisher : Nauka, Moscow.
Year : 1979.
Page : 192.

How to download it :
- use this link https://libarch.nmu.org.ua/handle/GenofondUA/43417 ,
- and transform the downloaded djvu file into a pdf file.

from Amazon

Phase transformations of elements under high pressure, 2005
(= update and extension of the 1979 Handbook)

Title : Phase transformations of elements under high pressure.
Authors : E. Yu Tonkov and E.G. Ponyatovsky.
Publisher : CRC Press.
Year : 2005 (or 2004 ?).
Page : 377.

How to download it :
(i) either via the official website using this address : https://doi.org/10.1201/9781420037609.
(ii) or via LibGen :
- enter "phase transformations of elements under high pressure",
- bingo !


2.c.3) Alloys and compounds : E. Yu Tonkov (a six-volume series 1992-2007 + a stand-alone volume 1998)

IMPORTANT NOTES :

(i) Let us stress that to the best of our knowledge this Handbook (made of 7 volumes) represents a UNIQUE LITERATURE COMPILATION of HIGH PRESSURE data for the PERIOD 1992 - 2007. And we will even quote E. Yu Tonkov about this aspect : "This Handbook is a unique work in the world literature that most completely summarizes available data on the phase transformations under high static and dynamic pressures published up to 2007." [taken from the Preface of Vol. 4].

(ii) The compilation presented below comprises 7 volumes which should be considered as a whole
in the sense that they are connected each other - a common practice in handbooks of phase diagrams made of several volumes. For instance, according to the table of content of Vol. 6, data for Li-H can be found in Vol. 3 and Vol. 7. Therefore, it is wise to own the 7 volumes.

(iii) The author has chosen to sort his 7 volumes in a certain way
It is an important detail, because in the tables of content, i.e. in the list of substances of each volume, it is sorted in this way. Thereby, this compilation is made with this spirit :
[1] Vol. 1 : High pressure phase transformations : a handbook (published in 1992)
[2] Vol. 2 : High pressure phase transformations : a handbook (published in 1992)
[3] Vol. 3 : High pressure phase transformations : a handbook (published in 1996)
[4] Vol. 4 : High pressure phase transformations : a handbook (with literature up to 2007)
[5] Vol. 5 : High pressure phase transformations : a handbook (with literature up to 2007)
[6] Vol. 6 : High pressure phase transformations : a handbook (with literature up to 2007)
[7] Vol. 7 : Compounds and alloys under high pressure : a handbook (published in 1998)

(iv) The Vol. 7 (Compounds and alloys under pressure) : a stand-alone volume
Although this volume is connected to the other 6 volumes (in the sense that these 6 volumes do refer to it) this Vol. 7 is a stand-alone book, a "desk edition" somehow. The idea here (as stressed by the author in the preface) is to have a volume with a more convenient format, where partial repetition of some data already presented in Vol 1 - Vol 3 (1992 - 1996) is made. Accordingly, it implies that the Vol. 7 compiles literature up to say, 1996, and not up to 2007 as Vol. 4 - Vol. 6 effectively do. It's why the table of content of Vol. 4 - Vol. 6 should be consulted in addition to that of Vol. 7 if one does not want the omission of any new data (which would have appeared in the period 1996 - 2007).

(v) Which Table of Content (TOC) should be consulted to find a given alloy (amongst the 7 volumes) ?!
To this question, one might draw two possible answers :
- either by consulting the TOCs of Vol. 4 - Vol. 6,
- or by consulting the TOC of Vol. 7 first, and then the TOCs in Vol. 4 - Vol. 6.
from Google Books

Vol. 1 - High pressure phase transformations, a Handbook

Substances covered in this volume : from Ag-containing alloys to Eu-containing alloys.
Author : E. Yu. Tonkov.
Publisher (first) : Gordon and Breach Science Publishers.
Year : 1992.
Page : 359.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 1 :
- from the publisher's website : https://www.routledge.com/High-Pressure-Phase-Transformations-Handbook-1/Tonkov/p/book/9782881247583.
- from LibGen : unfortunately, it is not yet available on LibGen.
- Note that a preview of this volume can be consulted using this Google Books link : https://books.google.fr/books?id=uo8wVw9Gq7wC&lpg=PP1&hl=fr&pg=PP1#v=onepage&q&f....
 
from Google Books

Vol. 2 - High pressure phase transformations, a Handbook

Substances covered in this volume : from F-containing alloys to Zr-containing alloys.
Author : E. Yu. Tonkov.
Publisher (first) : Gordon and Breach Science Publishers.
Year : 1992.
Page : 692.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 2 :
- from the publisher's website : surprisingly, this volume is not present at all in the publisher's website (at least, on Sept. 01st, 2024).
- from LibGen : unfortunately, it is not yet available on LibGen.
- Note that a preview of this volume can be consulted using this Google Books link : https://books.google.fr/books?id=G7HJAOFT7LMC&printsec=frontcover&hl=fr#v=onepage&q&....
 
from Google Books

Vol. 3 - High pressure phase transformations, a Handbook

Substances covered in this volume : from Ag-containing alloys to Zr-containing alloys. This volume is essentially a supplement to Vol. 1 and Vol. 2. It includes the data published between 1988 and 1992.
Author : E. Yu. Tonkov.
Publisher (first) : Gordon and Breach Science Publishers.
Year : 1996.
Page : 180.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 3 :
- from the publisher's website : surprisingly, this volume is not present at all in the publisher's website (at least, on Sept. 01st, 2024).
- from LibGen : unfortunately, it is not yet available on LibGen.
- Note that a preview of this volume can be consulted using this Google Books link : https://books.google.fr/books?id=d3PdnVFnibwC&printsec=frontcover&hl=fr&source=gbs_ge_su....
 
from our own copy

Vol. 4 - High pressure phase transformations, a Handbook

Substances covered in this volume : from Ag-containing alloys to Ca-containing alloys. This volume continues the three-volume series, with literature up to 2007.
Author : E. Yu. Tonkov.
Publisher : as far as we know, this volume has not been published yet. We are indebted to Dr. Vladimir Evgenievich Antonov (ISSP, RAS, Chernogolovka, Russia) for having supplied us with a copy of this volume (in Nov. 11th, 2022).
Page : 561.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 4 :
- from LibGen : enter "high pressure phase transformations",
- bingo !
N.B. : the version available on LibGen is that that has been supplied to us by Vlad Antonov.
 
from our own copy

Vol. 5 - High pressure phase transformations, a Handbook

Substances covered in this volume : from Ca-containing alloys to H-containing alloy. This volume continues the three-volume series, with literature up to 2007.
Author : E. Yu. Tonkov.
Publisher : as far as we know, this volume has not been published yet. We are indebted to Dr. Vladimir Evgenievich Antonov (ISSP, RAS, Chernogolovka, Russia) for having supplied us with a copy of this volume (in Nov. 11th, 2022).
Pages (total) : 609.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 5 :
- from LibGen : enter "high pressure phase transformations",
- bingo !
N.B. : the version available on LibGen is that that has been supplied to us by Vlad Antonov.
 
from our own copy

Vol. 6 - High pressure phase transformations, a Handbook

Substances covered in this volume : from H-containing alloys to Zr, plus Organic superconductors. This volume continues the three-volume series, with literature up to 2007.
Author : E. Yu. Tonkov.
Publisher : as far as we know, this volume has not been published yet. We are indebted to Dr. Vladimir Evgenievich Antonov (ISSP, RAS, Chernogolovka, Russia) for having supplied us with a copy of this volume (in Nov. 11th, 2022).
Pages (total) : 561.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 6 :
- from LibGen : enter "high pressure phase transformations",
- bingo !
N.B. : the version available on LibGen is that that has been supplied to us by Vlad Antonov.
 
from Amazon

Vol. 7 - Compounds and alloys under high pressure, a Handbook

Substances covered in this volume : binary alloys, pseudobinary and ternary alloys. This is a stand-alone volume (a desk edition). It is a partial repetition of some data already presented in Vol. 1 - Vol. 3 (1992 - 1996).
Author : E. Yu. Tonkov.
Publisher (first) : Gordon and Breach Science Publishers.
Year : 1998.
Page : 550.
Table of Content (TOC) : you can download it by clicking on the black box below.

How to download this volume 7 :
- from the publisher's website : https://www.routledge.com/Compounds-and-Alloys-Under-High-Pressure-A-Handbook/Tonkov/p/book/9789056990473.
- from LibGen : enter "compounds and alloys under high pressure", bingo !

Acknowledgements are due to Dr Daniel Fruchart for having informed us about this volume (email dated Nov. 04th, 2022). Thanks to that, we could afterwards be aware of all the other volumes produced by Tonkov.

3) Crystallographic data (handbooks)

Note that here : we do not address the PDF files (Powder Diffraction Files database), nor the IUCr TABLES,  both findable via LibGen.
We rather gather handbooks where lattice parameters can be found for many compounds (including binary and ternary Hydrides).

Photo from ebay

3.a) Pearson I, 1958

Title : A handbook of lattice spacings and structures of metals and alloys.
By : W.B. Pearson.
Year : 1958.
Pages : 1044.
Volume I.

How to download it :
- go to the "LibGen" website,
- and enter "lattice spacings and structures",
- bingo !

a photo of our own version

3.b) Pearson II, 1967

Title : A handbook of lattice spacings and structures of metals and alloys.
By : W.B. Pearson.
Year : 1967.
Pages : 1446.
Volume II.

How to download it :
- go to the "LibGen" website,
- and enter "lattice spacings and structures",
- bingo !
The version available in the LibGen website was scanned by The i2-HMR. It took us ... about 2 years and a half. Little by little, a few scanned pages a day, days after days, with some breaks, the book is now fully scanned and has just been uploaded in the LibGen website (Feb., 27th, 2023).
N.B. : at the time of the scan (that started in 2020), and still on Feb., 27th, 2023, this book is not available from Publishers, explaining why we shared it in LibGen. We're sorry for the low quality of the scan.

Photo by Iñaki del Olmo on Unsplash.

3.c) Pearson III, 1985 (ASM 1st Edition)

Title : Pearson's Handbook of Crystallographic Data for Intermetallic Phases.
Volumes : 1 - 3.
By : P. Villars and L.D. Calvert.
Year : 1985.
Pages : 3258.

This book is apparently not available for purchase in the ASM's website, and is not available yet in LibGen's website, unfortunately.

Photo from Amazon

3.d) Pearson IV, 1991 (ASM 2nd Edition)

Title : Pearson's Handbook of Crystallographic Data for Intermetallic Phases.
Volumes : 1 - 4.
By : P. Villars and L.D. Calvert.
Year : 1991.
Pages : 5366.

This book is apparently not available for purchase in the ASM's website, and is not available yet in LibGen's website, unfortunately.

photo from the ASM website

3.e) Pearson V, 1997 (ASM Desk Edition)

Title : Pearson's Handbook, Desk Edition, Crystallographic data for intermetallic phases.
Volumes : 1 - 2.
By : P. Villars.
Year : 1997.
Pages : 2886.

This book, not yet on LibGen, is however available for purchase in the ASM's website here.

Here's a non exhaustive list of what we plan to add :



- medium size review (general) on H in M.
- A section dealing with selected M-H systems :  Hydrogen Metal System I and II and maybe the last updates of the Ni-H(D) system.



... and many many many other things ...

15) Special Collection

 

15.a) Videos of brittle metals pulverized by the first H absorption

 
Introduction to 15.a.1 and 15.a.2 :
  • In this section 15.a, it is question of Hydride-forming intermetallic compounds.

  • Two examples of brittle metals are given : ZrMn1.5 and LaNi5.

  • As mentioned by D.P. Broom (1) "Most of the materials of practical interest  for storage applications decrepitate upon hydride phase formation, although some metallic hosts, such as Pd, do not.". This assertion perfectly illustrates that the formation of an Hydride does not necessarily means decrepitation (decrepitation = pulverization = the bulk host metal breaks up into fine powder). Note however that Pd (Palladium, Face-Centered Cubic) is a ductile metal and that the volumic mismatch between its Alpha phase (H-poor solid solution) and its Beta phase (H-rich solid solution) is about 9.8 % at RT, which is not that much.

  • That being said, most of the current Hydrogen storage compounds (being intermetallics) are brittle, so that decrepitation is difficult to avoid. But despite of its not-so-exciting connotations, the "decrepitation" aspect is actually of GREAT importance because it's a crucial part of the so-called "activation" process (of a given Hydrogen storage compound based on intermetallics). If you want to find out more about "activation" and "decrepitation", through the prism of intermetallics, we would advise you to consult e.g. :

 - section 3.1.4 pp. 79-81 (+ the ref [60] page 80) in : D.P. Broom's book mentioned here above in this webpage in section 1.e.9 ;

 - section 5.2.6 and 5.2.7 pp. 202-203 in : the book "H in intermetallic compounds II", 1992, mentioned here above in this webpage in section 1.e.2.

(1) in his 2011 book page 154. His book (Hydrogen storage materials, the characterization of their storage properties) can be found here above in section 1.e.9 in this webpage.



Introduction to 15.a.3 :
Importantly, we advise you to browse a recent (2024) review paper dealing with atomistic mechanisms that degrade metal hydrides during extended absorption/desorption cycling (decrepitation, sintering, hydrogen trapping, loss of crystallinity and disproportionation). Factors promoting degradation are also reviewed, and a detailed case study on LaNi5 is presented. See 15.a.3.
 

15.a.1) Video of ZrMn1.5 decrepitation

 
 
The above picture : a nice illustration of the pulverization (decrepitation) of a brittle host metal upon Hydride phase formation. Decrepitation is due to the big lattice parameter mismatch between that of the Hydride (H-rich solid solution) and that of the host metal (or rather that of the H-poor solid solution) together with the brittle character of the intermetallic alloy.
 
 
About the video :
Ph. Mauron, M. Bielmann, EMPA, Switzerland, 2004.
We warmly acknowledge Prof. Dr. Andreas Züttel for his kind permission, allowing this video to become public (email dated : December, the 4th, 2020) . Snapshots of this video can be found in slides 8-9 in the second presentation given by A. Züttel during the MH-2014 Summer School.

N.B. : while citing this video, please don't forget to acknowledge the two authors (with the institute EMPA), as well as A. Züttel (who is now at LMER, ISIC, SB, EPFL, all in Switzerland). Of course, a little thank to the i2-HMR would also be appreciated ;)

 

 

15.a.2) Video of LaNi5 decrepitation

As in the above section (15.a.1), we are VERY PLEASED to make such precious movies available to the public. These kind of records are super difficult to be found, and constitute very good didactic materials for people not yet familiarized with the H-induced pulverization phenomenon.

Here, the idea is the same than with ZrMn1.5 : the first H absorption pulverizes the intermetallic compound. This process is called "activation" (as described in the video).

Snapshot from the movie
 

Snapshots from the video. All the experimental details are precisely described in the movie (including the sound produced by the decrepitation !).

In addition to LaNi5, two alloys are presented : LaNi4.9Si0.1 and LaNi4.9Cu0.1.


 

Details about the video :

Title : Activation of a LaNi5 hydrogen absorbent.
Scientific collaborators : H.H. van Mal, H.A. van Esveld, H. Zijlstra.
Script : N. Wiedenhof, H. Zijlstra.
Photography, editing and direction : P.G.M. Vos.
Animation : W. Rouvoet.
Production :
      Photonics Department
      Philips Research Laboratories
      Eindhoven, Netherlands, 1973.

 

Acknowledgements (including to Philips) :

First of all, we sincerely acknowledge Philips for letting us the possibility to make their movie available on our website "for educational and non-commercial purposes only" (email dated : April, the 7th, 2021). We also warmly thank our Philips contact, Willem van de Leest, for his always-very-cordial-and-prompt emails.

Sincere and warm acknowledgements are also due to Daniel FRUCHART (Directeur de Recherche Emérite, Institut Néel, Grenoble, France) for having informed us about the existence of this super movie, back in 2016. Thank you so much !!


N.B. : while citing this video, please don't forget to mention the above details (see "Details about the video").
Of course, a little thank to the i2-HMR would also be appreciated ;)

 

 
15.a.3) a recent (2024) review about degradation mechanisms observed in interstitial metal hydrides for H storage
 
In addition to the above 15.a.1 and 15.a.2, we advise you to browse a recent (2024) review paper dealing with atomistic mechanisms that degrade metal hydrides during extended absorption/desorption cycling (decrepitation, sintering, hydrogen trapping, loss of crystallinity and disproportionation). Factors promoting degradation are also reviewed, and a detailed case study on LaNi5 is presented.
Click on the above picture to reach the Elsevier's page.
---> Degradation of metal hydrides in hydrogen-based thermodynamic machines: A review,
Fatema Tuz Zohra, Colin J. Webb, Krystina E. Lamb, Evan MacA. Gray,
International Journal of Hydrogen Energy, Volume 64, 25 April 2024, Pages 417-438.
Table of Content

Figures extracted from the cited-above review article :

Fig. 12. Combined effects of prolonged cycling, extreme operating condition, and impurity presence on the degradation mechanism.







Fig. 17. Decrepitation of an ingot of LaNi5 with hydrogenation at a hydrogen pressure of 40 atm. (a) Initial state; (b) after 10 h; (c), (d), (e) decrepitated state after 1.5 h; (f) activated state.

N.B. : the reference for this picture is [van Mal H.H.. Stability of ternary hydrides and some applications. Doctoral Dissertation, Technol. Univ. Delft 1976]. This Author is actually amongst the Authors who produced the video shown in the above section 15.a.2.


 

15.b) History of
International Symposiums on
Metal - Hydrogen systems

MH-2010, in RUSSIA : http://www.mh2010.com
MH-2012, in JAPAN : http://www.mh2012.jp
MH-2014, in UK : http://mh2014.salford.ac.uk/
MH-2016, in SWITZERLAND : https://mh2016.ch/
MH-2018, in CHINA : http://www.mh2018.cn/
MH-2020 (in 2022), in AUSTRALIA : http://www.metal-hydrogen2022.com/
MH-2024, in FRANCE : https://mh2024.org/
MH-2026, in JAPAN : https://mh2026.jp/



Message to Organizers of previous Conferences (MH-2018, MH-2016, MH-2012) :

regretfully, your website can't be accessed (July, 21st, 2020). Would it be possible to make it accessible again, please ?

picture taken from the MH-2014 website

15.c) History of GRC / GRS Conferences

Hydrogen - Metal systems Gordon Research Conferences GRC
can be found HERE.
Hydrogen - Metal systems Gordon Research Seminars GRS
can be found HERE.

The next Conferences will be held in Switzerland in 2025 :
GRC
GRS

We need help from long-experienced researchers in the M-H field :


 typically with this page.
If you're willing to contribute, please don't hesitate to get connect with us !!!!
* contact@i2-hmr.com
**
***
N.B. : all papers / chapters / books mentioned in this page can be downloaded via LibGen or Sci Hub
(except : those directly downloadable thanks to the blue/black boxes, or a few exceptions).
Via Sci-Hub : just enter the DOI number, bingo !
Via Libgen : just enter the keys words, bingo !

* from the movie "Back to the future".

** a character in : https://en.wikipedia.org/wiki/Once_Upon_a_Time..._Life

*** last picture (representing a Hydride, in the sense H-rich phase) : taken from https://www.sciencedirect.com/science/article/pii/S1369702103009222